Samuel Melaku, , Vernon Morris, Dharmaraj Raghavan, Charles Hosten
Seasonal variation of heavy metals in ambient air and precipitation at a single site in Washington, DC
Environmental Pollution, Volume 155, Issue 1, September 2008, Pages 88–98
ISSN: 0269-7491
http://www.worldcat.org/oclc/15211864Samuel Melaku Department of Chemistry, Howard University, 525 College Street, NW Washington, DC 20059, USA
Corresponding author. Tel.: +1 202 865 8536; fax: +1 202 806 5442.
samuelmelaku@yahoo.com
Vernon Morris Department of Chemistry, Howard University, 525 College Street, NW Washington, DC 20059, USA
Dharmaraj Raghavan Department of Chemistry, Howard University, 525 College Street, NW Washington, DC 20059, USA
Charles Hosten Department of Chemistry, Howard University, 525 College Street, NW Washington, DC 20059, USA
"Abstract
Atmospheric samples of precipitation and ambient air were collected at a single site in Washington, DC, for 7 months (for ambient air samples) and 1 year (for wet deposition samples) and analyzed for arsenic, cadmium, chromium and lead. The ranges of heavy metal concentrations for 6-day wet deposition samples collected over the 1-year period were 0.20–1.3 µg/l, 0.060–5.1 µg/l, 0.062–4.6 µg/l and 0.11–3.2 µg/l for arsenic, cadmium, chromium and lead, respectively, with a precision better than 5% for more than 95% of the measurements. The ranges of heavy metal concentrations for the 6-day ambient air samples were 0.800–15.7 ng/m3, 1.50–30.0 ng/m3, 16.8–112 ng/m3, and 2.90–137 ng/m3 for arsenic, cadmium, chromium and lead, respectively, with a precision better than 10%. The spread in the heavy metal concentration over the observation period suggests a high seasonal variability for heavy metal content in both ambient air and wet deposition samples.
Keywords
Wet deposition; Ambient air; Metals"
http://www.sciencedirect.com/science/article/pii/S0269749107005313